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    高師機構典藏 NKNUIR > 理學院 > 化學系 > 博碩士論文 >  Item 987654321/15376
    Please use this identifier to cite or link to this item: http://ir.nknu.edu.tw/ir/handle/987654321/15376


    題名: 1,1`-雙薁苯取代基掌性輔助劑之合成、性質及應用研究
    Authors: 郭育成
    貢獻者: 陳阿煌
    Arh-Hwang Chen
    Keywords: 掌性輔助劑;雙薁
    Date: 2002-08-02
    Issue Date: 2011-05-30 16:54:13 (UTC+8)
    Abstract: 本篇論文在研究掌性輔助劑1,1’-二(2-胺基-4-苯基薁-1-羧酸乙酯) (195)的合成。我們以二環戊二烯(170)為起始,合成具1、2、3三取代基的2-胺基薁-1,3-二羧酸乙酯(175)的骨架之後,利用一次與格里鈉試劑的親核性反應,讓薁七圓環接上苯基,並探討反應結果及產物之間的光譜差異。獲得2-乙醯胺-4-苯基薁-1-羧酸乙酯(193)後,進一步研究合成2-胺基-4-苯基薁-1-羧酸乙酯(194)。期使以此為前趨物合成1,1’-二(2-胺基-4-苯基薁-1-羧酸乙酯)(195)。
    Appears in Collections:[化學系] 博碩士論文

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